Publikationen
Epoxy Based Carbon Fiber Reinforced Plastics Recycling via Solvolysis with Non-Oxidizing Methanesulfonic Acid.
Zhang, X.; Sibari, R.; Chakraborty, S.; Baz, S.; Gresser, G. T.; Benner, W.; Brämer, T.; Steuernagel, L.; Ionescu, E.; Deubener, J.; Beuermann, S.; Ziegmann, G.; Wilhelm, R. Chem. Ing. Tech. 2024, 96, in press.
Catalytic Recycling of Thermoset Carbon Fiber-Reinforced Polymers (CFRPs).
Torkaman, N.; Bremser, W.; Wilhelm, R. ACS Sustainable Chem. Eng. 2024, 12, DOI: 10.1021/acssuschemeng.3c06613.
2023
Macromolecular Architecture-Dependent Polymorphous Crystallization Behavior of PVDF in the PVDF/γ-BL System via Thermally Induced Phase Seperation.
Gaßdorf, F.; Fan, Z.; Schwaderer, S.; Beuermann, S.; Wilhelm, R.; Weber, A. P.; Fischlschweiger, M. Macromol. Rapid Commun. 2023, 2300177.
Straightforward Synthesis of Chiral Sulfonate Based Ionic Liquids from Amino Alcohols for Chiral Recognition.
Feuge, N.; Wilhelm, R. Chirality 2023, 35, 993-1011.
Characterization of an Aqueous Flow Battery Utilizing a Hydroxylated Tetracationic Viologen and a Simple Cationic Ferrocene Derivative.
Caianiello, C.; Arenas, L. F.; Turek, T.; Wilhelm, R. Adv. Energy Sustainability Res. 2023, 4, 2300077.
Rutile, Anatase, Brookite and Titania Thin Film from Hubbard Corrected and Hybrid DFT.
Badalov, S. V.; Bocchini, A.; Wilhelm, R.; Kozub, A. I.; Gerstmann, U.; Schmidt, G. W. Mater. Res. Express 2023, 10, 075501.
Synthesis of New Graphene Oxide/TiO2 and TiO2/SiO2 Nanocomposites and Their Evaluation as Photocatalysts.
Rosenthal, M.; Biktagirov, T.; Schmidt, W. G.; Wilhelm, R. Catal. Sci. Technol. 2023, 13, 4367-4377. Back Cover on page 4570.
Diquat based Dyes: A new Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation.
Meier, A.; Badalov, S. V.; Biktagirov, T.; Schmidt, W. G.; Wilhelm, R. Chem. Eur. J. 2023, 29, e202203541. Cover Feature on Page e202300788.
A Hydroxylated Tetracationic Viologen Based on Dimethylaminoethanol as a Negolyte for Aqueous Flow Batteries.
Caianiello, C.; Arenas, L. F.; Turek, T.; Wilhelm, R. Batteries & Supercaps 2023, 6, e202200355. Cover Feature on Page e202200540.
2022
Influencing the Froth Flotation of LiAlO2 and Melilite Solid Solution with Ionic Liquids.
Qiu, H.; Degenhardt, C.; Feuge, N.; Goldmann, D.; Wilhelm, R. RSC Adv. 2022, 12, 29562-29568.
Unique Enantiopure Camphor-Based Neutral Arene-Ruthenium(II) Complexes: DNA/BSA Binding, Kinetic and Cytotoxic Studies.
Milutinovic, M. M.; Cakovic, A. Z.; Cocic, D.; Rais, E.; Schloch, R.; Markovic, B. S.; Arsenijevic, N.; Volarevic, V.; Jovanovic-Stevic, S.; Bogojeski, J. V.; Wilhelm, R. J. Coord. Chem. 2022, 75, 1636-1655.
Intramolecular Phosphine-Promoted Knoevenagel Based Redox-Reaction.
Feuge, N.; Namysko, J. C.; Kaufmann, D. E.; Wilhelm, R. Molecules 2022, 27, 4875.
Reversible Functionalization and Exfoliation of Graphite by a Diels-Alder Reaction with Furfuryl Amine.
Torkaman, N. F.; Kley, M.; Bremser, W.; Wilhelm, R. RSC Adv. 2022, 12, 17249-17256.
On the Influence of a Camphor-based 1,3-Diamine Fragment in a Proline-Based Organocatalyst.
Babkova, M.; Wilhelm, R. ChemistrySelect 2022, 7, e202201313.
2021
Improvement of the Froth Flotation of LiAlO2 and Melilite solid solution via Pre-Functionalization.
Qiu, H.; Kersebaum, J.; Wollmann, A.; Feuge, N.; Haas, A. Goldmann, D.; Wilhelm, R. Scientific Reports 2021, 11, 20443.
On the Influence of Carbon Nanoparticles as Additives in the Electrosynthesis of Bromoarenes.
Pippert, F.; Wilhelm, R. Carbon Trends 2021, 4, 100075.
2020
A Photoredox Catalysed Heck Reaction via Hole Transfer From a Ru(II)-bis(terpyridine) Complex to Graphene Oxide.
Rosenthal, M.; Lindner, J. K. N.; Gerstmann, U.; Meier, A.; Schmidt, W. G.; Wilhelm, R. RSC Adv. 2020, 10, 42930-42937. Highlighted in Synfacts 2021, 17, 311.
Photocatalytic Properties of Graphene-Supported Titania Clusters from Density-Functional Theory.
Badalov, S. V.; Wilhelm, R.; Schmidt, W. G. J. Comput. Chem. 2020, 41, 1921-1930.
Tetraalkylammonium-Based Ionic Liquids for a RuCl3 Catalysed C-H-Activated Homocoupling.
Muntzeck, M.; Pippert, F.; Wilhelm, R. Tetrahedron 2020, 76, 131314.
2019
Straightforward Immobilization of Phosphonic Acids and Phosphoric Acid Esters on Mesoporous Silica and their Application in an Asymmetric Aldol Reaction.
Weinberger, C.; Heckel, T.; Schnippering, P; Schmitz, M.; Guo, A.; Keil, W.; Marsmann, H.C.; Schmidt, C.; Tiemann, M.; Wilhelm, R. Nanomaterials 2019, 9, 249-260.
2018
Determination of the Refractive Indices of Ionic Liquids by Ellipsometry, and their Application as Immersion Liquids.
Wu, X.; Muntzeck, M.; De Los Acros, T; Grundmeier, G.; Wilhelm, R.; Wagner, T. Appl. Opt. 2018, 57, 9215-9222.
Protic Ionic Liquids as Catalysts for a Three-Component Coupling/Hydroarylation/Dehydration Tandem Reaction.
Muntzeck, M.; Wilhelm, R. Z. Naturforsch. 2018, 73b, 515–519.
Graphene Oxide as Flexibilizer for Epoxy Amine Resins.
Wolk, A.; Rosenthal, M.; Weiß, J.; Voigt, M.; Wesendahl, J.; Hartmann, M.; Grundmeier, G.; Wilhelm, R.; Meschut, G.; Tiemann, M.; Bremser, W. Prog. Org. Coat. 2018, 122, 280-289.
A Novel Lubricant Based on Covalent Functionalized Graphene Oxide Quantum Dots.
Wolk, A.; Rosenthal, M.; Neuhaus, S.; Huber, K.; Brassat, K.; Lindner, J. K. N.; Grothe, R.; Grundmeier, G.; Bremser, W.; Wilhelm, R. Scientific Reports 2018, 8, 5843.
A Camphor Based 1,3-Diamine Ru(II) Terpyridine Complex: Synthesis, Characterization, Kinetic Investigation and DNA Binding.
Milutinović, M. M.; Bugarčić, Z. D.; Wilhelm, R. New. J. Chem. 2018, 42, 7607-7611.
New Pyridinium Based Ionic Dyes for the Hydrogen Evolution Reaction.
Konieczna, D. D.; Biller, H.; Witte, M.; Schmidt, W. G.; Neuba, A.; Wilhelm, R. Tetrahedron 2018, 74, 142-149.
2017
Reactivity of Grubbs-Hoveyda II Complexes including Extended N-Heterocyclic Carbenes with a Bicyclic Camphor-Based Framework.
Rais, E.; Flörke, U.; Wilhelm, R. Synthesis 2017, 49, 2852-2864.
A Sophisticated Approach towards a New Class of Copper(I)-Sulfur Cluster Complexes with Imidazolinium-Dithiocarboxylate Ligands.
Ortmeyer, J.; Flörke, U.; Henkel, G.; Wilhelm, R.; Neuba, A. Eur. J. Inorg. Chem. 2017, 3191-3197.
The Use of Stable Carbene-CO2 Adducts for the Polymerization of Trimethylene Carbonate.
Reitz, A. K.; Sun, Q.; Wilhelm, R.; Kuckling, D. J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 820-829.
2016
Synthesis and Investigation of New Cyclic Haloamidinium Salts.
Rais, E.; Flörke, U.; Wilhelm, R. Z. Naturforsch. 2016, 71b, 667-676.
Straightforward Diastereoselective Synthesis of P-chirogenic (1R)-1,8,8-Trimethyl-2,4-diaza-3-phosphabicyclo[3.2.1]octane 3-Oxides. Application as Chiral NMR Solvating Agents.
Uzarewicz-Baig, M.; Wilhelm, R. Heteroatom Chem. 2016, 27, 121-134.
Influence of Ionic Liquids on an Iron(III) Catalyzed Three-Component Coupling/Hydroarylation/Dehydrogenation Tandem Reaction.
Muntzeck, M.; Wilhelm, R. Int. J. Mol. Sci. 2016, 17, 860-868.
2015
Chiral Imidazolinium Salts with TIPS Groups for the Palladium Catalyzed alpha-Arylation and as Chiral Solvating Agents.
Gilani, M. A.; Rais, E.; Wilhelm, R. Synlett 2015, 26, 1638-1641.
Crystal Structure of Tris(1,3-dimesityl-4,5-dihydro-1H-imidazol-3-ium) tetrabromidocobaltate(II) bromide chloroform hexasolvate.
Rais, E.; Flörke, U.; Wilhelm, R. Acta Cryst. 2015, E71, m177-m178.
Crystal Structure of Dibromidobis(1,3-dibenzyl-1,3-diazinan-2-one-κO)cobalt(II).
Rais, E.; Flörke, U.; Wilhelm, R. Acta Cryst. 2015, E71, m160-m161.
Crystal structures of diiodidobis[(1S,5S )-4-mesityl-1,2,8,8-tetramethyl-2,4-diazabicyclo[3.2.1]octan-3-ylidene-κC3]palladium(IV) and dichlorido[(1S,5S )-4-mesityl-1,2,8,8-tetramethyl-2,4-diazabicyclo[3.2.1]octan-3-ylidene-κC3](triphenylphosphane-κP )palladium(IV).
Rais, E.; Flörke, U.; Wilhelm, R. Acta Cryst. 2015, E71, 919-922.
Synthesis of New Camphor-Based Carbene Ligands and Their Application in a Copper Catalyzed Michael Addition with B2Pin2.
Koppenwallner, M.; Rais, E.; Uzarewicz-Baig, M.; Tabassum, S.; Gilani, M. A.; Wilhelm, R. Synthesis 2015, 47, 789-800.
Synthesis of New Copper(I) Based Linear 1-D-Coordination Polymers with Neutral Imidazolinium-Dithiocarboxylate Ligands.
Neuba, A.; Ortmeyer, J.; Konieczna, D. D.; Weigel, G.; Flörke, U.; Henkel, G.; Wilhelm, R. RSC Adv. 2015, 5, 9217-9220.
2014
Highly Regioselective Synthesis of Chiral Diamines via a Buchwald-Hartwig Amination from Camphoric Acid and their Application in the Henry Reaction.
Uzarewicz-Baig, M.; Koppenwallner, M.; Tabassum, S.; Wilhelm, R. Appl. Organometal. Chem. 2014, 28, 552-559.
Investigation of Imidazol(in)ium-dithiocarboxylates as Sensors for the Detection of Mercury(II) and Silver(I) Ions.
Konieczna, D. D.; Blanrue, A.; Wilhelm, R. Z. Naturforsch. 2014, 69b, 596-604.
2013
Ring Opening Polymerization of Organic Carbonates Using CO2-Carbene Adducts as Effective Organocatalyst.
Reitz, A.; Wilhelm, R.; Kuckling D. Macromol. Symp. 2013, 334, 92-97.
Chiral Ionic Liquids Based on Nicotine for the Chiral Recognition of Carboxylic Acids.
Heckel, T.; Winkel, A.; Wilhelm, R. Tetrahedron: Asymmetry 2013, 24, 1127-1133.
An Ionic Liquid Solution of Chitosan as Organocatalyst.
Heckel, T.; Konieczna, D. D.; Wilhelm, R. Catalysts 2013, 3, 914-921.
Invited book chapter: Non-covalent Activation - Lewis Acids.
Heckel, T.; Wilhelm, R. in Comprehensive Enantioselective Organocatalysis, ed. Dalko, P. I.; Wiley-VCH, Weinheim, 2013, p. 413.
2012
Imidazolinium and Amidinium Salts as Lewis Acid Organocatalysts.
Sereda, O.; Clemens, N.; Heckel, T.; Wilhelm, R. Beilstein J. Org. Chem. 2012, 8, 1798-1803.
2011
Imidazolinium Sulfonate and Sulfamate Zwitterions as Chiral Solvating Agents for Enantiomeric Excess Calculation.
Tabassum, S.; Gilani; M.; Wilhelm, R. Tetrahedron: Asymmetry 2011, 22, 1632-1639.
2010
New Chiral Ionic Liquids Based on Enantiopure Sulphate and Sulfonate Anions for Chiral Recognition.
Winkel, A.; Wilhelm, R. Eur. J. Org. Chem. 2010, 5817-5824.
Invited Review: Lewis Acid Organocatalysts.
Sereda, O.; Tabassum, S.; Wilhelm, R. Top. Curr. Chem. 2010, 291, 349-393.
2009
New Chiral Ionic Liquids Based on Imidazolinium Salts.
Winkel, A.; Wilhelm, R. Tetrahedron: Asymmetry 2009, 20, 2344-2350.
New Enantiopure NHCs Derived from Camphor.
Reddy, P. V. G.; Tabassum, S.; Blanrue, A.; Wilhelm, R. Chem. Commun. 2009, 5910-5912.
Hindered Brønsted Bases as Lewis Base Catalysts.
Tabassum, S.; Sereda, O.; Reddy, P. V. G.; Wilhelm, R. Org. Biomol. Chem. 2009, 7, 4009-4016.
Enantiopure Imidazolinium Dithiocarboxylates as Highly Selective Novel Organocatalysts.
Sereda, O.; Blanrue, A.; Wilhelm, R. Chem. Commun. 2009, 1040-1042.
Methylated Imidazolinium-Dithiocarboxylates: Two Representatives of a New Class of Ionic Liquids.
Blanrue, A.; Wilhelm, R. Synthesis 2009, 583-586.
2008
New Enantiopure Imidazolinium Carbene Ligands Incorporating Two Hydroxy Groups for Lewis Acid Catalyzed Diethyl Zinc Addition to Aldehydes.
Gilani, M.; Wilhelm, R. Tetrahedron: Asymmetry 2008, 19, 2346-2352.
Influence of the Substitution Pattern of Cp-Iron-Arene Salts in the Solid-State Synthesis of New Carbon Nanostructures.
Winkel, A.; Jain, D.; Wilhelm, R. Organometallics 2008, 27, 3430-3434.
Invited Review: Recent Advances in the Synthesis and Application of Chiral Ionic Liquids.
Winkel, A.; Reddy, P. V. G.; Wilhelm, R. Synthesis 2008, 999-1016.
2007
Hexamethyldisilazane Sodium Salt as Highly Active Lewis Base Catalyst for the Staudinger Reaction.
Sereda, O.; Wilhelm, R. Synlett 2007, 3032-3036.
Invited Paper: Solid-State Synthesis of Carbon-Nanostructures.
Wilhelm, R.; Winkel, A.; Jain, D. J. Fudan University (Natural Science) 2007, 46, 701-702.
An Easy Way to Produce a-Iron Filled Multiwalled Carbon Nanotubes.
Jain, D.; Wilhelm, R. Carbon 2007, 45, 602-606.
2006
Easy Accessible Chiral Bis-Hydroxy Imidazolinium Salts as Shift Reagents and Carbene Precursors.
Jurčík, V.; Gilani, M.; Wilhelm, R. Eur. J. Org. Chem. 2006, 5103-5109.
Preparation of New Enantiopure Imidazolinium Salts and Their Evaluation as Catalysts and Shift Reagents.
Jurčík, V.; Wilhelm, R. Tetrahedron: Asymmetry 2006, 17, 801-810.
Unexpected Behaviour of Tosylated and Acetylated Imidazolinium Salts. Clemens, N.; Sereda, O.; Wilhelm, R. Org. Biomol. Chem. 2006, 4, 2285-2290.
Solid-State Synthesis of Well Defined Carbon Nanocapsules from Organometallic Precursors.
Jain, D.; Winkel, A.; Wilhelm, R. Small 2006, 2, 752-755.
2005
Synthesis of Enantiopure Tricarbonyl(indan-1,2-dione)chromium.
Leinweber, D.; Weidner, I.; Wilhelm, R.; Wartchow, R.; Butenschön, H. Eur. J. Org. Chem. 2005, 5224-5235.
An Imidazolinium Salt as Ionic Liquid for Medium and Strong Bases.
Jurčík, V.; Wilhelm, R. Green Chem. 2005, 7, 844-848.
Imidazolinium Salts as Catalysts for the aza-Diels-Alder Reaction.
Jurčík, V.; Wilhelm, R. Org. Biomol. Chem. 2005, 3, 239-244.
2004
Imidazolinium-Carbodithioate Zwitterions as Organocatalysts for the Cyanosilylation of Aldehydes.
Blanrue, A.; Wilhelm, R. Synlett 2004, 2621-2623.
Preparation of Aminals in Water.
Jurčík, V.; Wilhelm, R. Tetrahedron 2004, 60, 3205-3210.
2003
Near-Quantitative Solid-State Synthesis of Carbon Nanotubes from Homogeneous Diphenylethynecobalt and -Nickel Complexes.
Iyer, V. S.; Vollhardt, K. P. C.; Wilhelm, R. Angew. Chem. 2003, 115, 4515-4519; Angew. Chem. Int. Ed. 2003, 42, 4379-4383.
Palladium Catalysed Suzuki Reactions of Fluoroarenes.
Widdowson, D. A.; Wilhelm, R. Chem. Commun. 2003, 578-579.
2002
A Computational Study of the Mechanism of Palladium Insertion into Alkynyl and Aryl Carbon–Fluorine Bonds.
Jakt, M.; Johannissen L.; Rzepa, H. S.; Widdowson, D. A.; Wilhelm, R. J. Chem. Soc., Perkin Trans. 2 2002, 576-581.
The Tricarbonylchromium Complex of a Trimethyltin-Substitued N‑(Triisopropylsilyl)indole - A Dynamic NMR Study of Multiple Independent Rotation Processes in the Solid State with an X-ray Diffraction Structure and Molecular Mechanics Calculations.
Aliev, A. E.; Anderson, J. E.; Butler, D.; Gonzalez-Quteirino, J.; Lunazzi, L.; Mazzanti, A.; Steed, J. W.; Wilhelm, R. Eur. J. Inorg. Chem. 2002, 133-140.
2001
Dilithiation of Arenetricarbonylchromium(0) Complexes with Enantio-selective Quench: Application to Chiral Biaryl Synthesis.
Tan, Y.-L.; White, A. J. P.; Widdowson, D. A.; Wilhelm, R.; Williams, D. J. J. Chem. Soc., Perkin Trans. 1 2001, 3269-3280.
Reversal of Asymmetric Induction in Arenetricarbonylchromium(0) Complexes via Dilithiation with the (–)-Sparteine / BuLi System and Enantioselective Quench.
Tan, Y.-L.; Widdowson, D. A.; Wilhelm, R. Synlett 2001, 1632-1634.
Asymmetric Synthesis of a Fully Protected ent-Actinoidinic Acid.
Wilhelm, R.; Widdowson, D. A. Org. Lett. 2001, 3, 3079–3082.
2000
Asymmetric Deprotonation – Substitution of Arenetricarbonylchromium(0) Complexes: Substituent Controlled Lithiation with the Butyllithium-Sparteine System.
Wilhelm, R.; Sebhat, I. K.; White, A. J. P.; Williams, D. J.; Widdowson, D. A. Tetrahedron: Asymmetry 2000, 11, 5003-5016.
Palladium Catalyzed Cross-coupling of (Fluoroarene)tricarbonylchromium(0) Complexes.
Wilhelm, R.; Widdowson, D. A. J. Chem. Soc., Perkin Trans. 1 2000, 3808-3813.
Directed Lithiation in Arenetricarbonylchromium(0) Complexes: Assessment of Some Directing Group Specificities and of Electrophilic Quench Efficancies.
Sebhat, I. K.; Tan, Y.-L.; Widdowson, D. A.; Wilhelm, R.; White, A. J. P.; Williams, D. J. Tetrahedron 2000, 56, 6121-6134.
1999
Palladium Catalyzed Cross-coupling of (Fluoroarene)tricarbonylchromium(0) Complexes.
Widdowson, D. A.; Wilhelm, R. Chem. Commun. 1999, 2211-2212.